Új pd-komplexek azometin-származékokkal, és fizikai-kémiai vizsgálatuk

Várhelyi, Csaba and Nagy, Renáta Ildikó and Pokol, György and Szalay, Roland and Mihály, Judith and Goga, Firuţa and Golban, Ligia Mirabela: Új pd-komplexek azometin-származékokkal, és fizikai-kémiai vizsgálatuk. Proceedings of the International Symposium on Analytical and Environmental Problems, (21). pp. 8-11. (2015)

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Abstract

In our research we synthesized novel [Pd(monophenyl-dioxime)2L2] (L = 2-aminopyrimidine, 3-hydroxi-aniline, lepidine) type complexes and with different Schiff-bases: [Pd(acetonyl-acetone)2(diamine)], [Pd(dibenzoyl-methane)2(diamine)] (diamine = ophenylene-diamine, ethylene-diamine, 1,2-, 1,3-propylene-diamine) by reacting PdCl2, monophenyl-dioxime, respectively Schiff-bases with amine, respectively diamine in the corresponding solvent. We analyzed their physicochemical properties using mass spectrometry, infrared-, NMR-spectroscopy and thermal analysis (TG, DTG and DTA). The Pd-complexes have an important role in many organic chemistry reactions as catalysts [1]. Some of them are used in industry. The Pd precious metal price is high, but compared with Rh, Pt, Ir, or Os is infinitesimal. Regarding the biological activity, they inhibit some enzymes which are important in anti-diabetic therapy. Some of the Pd(II) complexes are anti-glaucoma drug candidates [2]. Due to the similarity between Pd and Pt, the complexes of palladium(II) can be considered as potential anticancer agents [3].

Item Type: Article
Journal or Publication Title: Proceedings of the International Symposium on Analytical and Environmental Problems
Date: 2015
Volume: 21
Page Range: pp. 8-11
ISBN: 978-963-306-411-5
Uncontrolled Keywords: Kémia
Additional Information: Bibliogr.: 11. p. ; összefoglalás angol nyelven
Date Deposited: 2018. Dec. 04. 14:18
Last Modified: 2018. Dec. 13. 13:34
URI: http://acta.bibl.u-szeged.hu/id/eprint/55915

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