Deveseleanu-Corîci Livia; Şova Sergiu; Badea Valentin; Costisor Otilia; Cseh Liliana: Chemistry and photochemistry of novel aromatic spiroketals derived from 2,6-bis(5-bromo-2-hydroxybenzylidene) cyclohexanone.
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Absztrakt (kivonat)
Natural colorants such as flavylium and xanthylium derivatives have attracted considerable interest in the last decades due to their potential health effects and replacement of synthetic pigments. In addition, these type of compounds exhibit versatile photochromic properties by switching from a variety of colourswhen submitted to different external stimuli[1-3]. The aim of the present work was to design novel photochromic systems based on xanthylium derivatives. Therefore, we have synthesized and characterized 2,6-bis(5-bromo-2- hydroxybenzylidene)cyclohexanone. The network of chemical reactions when submitted to light and different pH values has been investigated. A new colorless compound 3,11-dibromo7,8-dihydro-6H-chromeno[3,2-d]xanthenes(Scheme 1) isolated from the equilibrated solution of trans-chalcone specie in methanolhave been isolated and fully characterized by NMR and X-ray diffraction. The rate of the reaction increased when the solution of trans-chalcone was exposed to sunlight. The spiroketal form was stable at in neutral and basic conditions, while at low pH values it converts into xantylium cationic form.
| Mű típusa: | Konferencia vagy workshop anyag |
|---|---|
| Befoglaló folyóirat/kiadvány címe: | Proceedings of the International Symposium on Analytical and Environmental Problems |
| Dátum: | 2016 |
| Kötet: | 22 |
| ISBN: | 978-963-306-507-5 |
| Oldalak: | p. 124 |
| Konferencia neve: | International Symposium on Analytical and Environmental Problems (22.) (2016) (Szeged) |
| Befoglaló mű URL: | http://acta.bibl.u-szeged.hu/55893/ |
| Kulcsszavak: | Kémia - előadáskivonat |
| Megjegyzések: | Bibliogr.: 124. p. ; összefoglalás angol nyelven |
| Feltöltés dátuma: | 2018. dec. 11. 14:10 |
| Utolsó módosítás: | 2022. aug. 08. 15:48 |
| URI: | http://acta.bibl.u-szeged.hu/id/eprint/56054 |
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