Transformation of atrazin by different advanced oxidation processes

Rózsa Georgina and Fazekas Ákos and Schrantz Krisztina and Alapi Tünde and Oppeländer Thomas and Takács Erzsébet and Wojnárovits László: Transformation of atrazin by different advanced oxidation processes.

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Abstract

In this work ultraviolet photolysis (UV) and three advanced oxidation processes (AOPs), vacuum ultraviolet (VUV) photolysis, ultraviolet photolysis combined with vacuum ultraviolet photolysis (UV/VUV) and gamma (γ) radiolysis were used for the generation of reactive primary free radicals (hydroxyl radical (•OH), hydrated electron (eaq ), hydrogen radical (•H)) to induce the transformation of atrazine in aqueous solution. We examined different reaction conditions (solutions of atrazine saturated with dissolved oxygen or nitrogen). The aim of this work is the comparison of the oxidative transformation of atrazine during UV (254 nm), UV/VUV (254/185 nm) and VUV (172 nm) photolysis, as well as γ radiolysis. The efficiency of the photolytic methods increased in the following order: UV< VUV< UV/VUV photolysis. The economic efficiency of the used processes was compared based on Electric Energy per Order (EEO). γ radiolysis was found to be the economically most feasible method compared to UV/VUV, VUV and UV photolysis.

Item Type: Conference or Workshop Item
Journal or Publication Title: Proceedings of the International Symposium on Analytical and Environmental Problems
Date: 2017
Volume: 23
ISBN: 978-963-306-563-1
Page Range: pp. 51-55
Event Title: International Symposium on Analytical and Environmental Problems (23.) (2017) (Szeged)
Related URLs: http://acta.bibl.u-szeged.hu/55894/
Uncontrolled Keywords: Analitikai kémia
Additional Information: Bibliogr.: p. 54-55. ; összefoglalás angol nyelven
Date Deposited: 2018. Dec. 14. 08:12
Last Modified: 2022. Aug. 08. 15:49
URI: http://acta.bibl.u-szeged.hu/id/eprint/56154

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