Determination and uncertainty analysis of inorganic arsenic in rice by UHPLC-ICPMS

Rangasamy Rajesh and Malekadi Praveen Kumar and Mohamed D. Peer and Tyagi Dheeraj Kumar and Raveendran Rahul and Gupta Ananda: Determination and uncertainty analysis of inorganic arsenic in rice by UHPLC-ICPMS. In: Acta biologica Szegediensis, (64) 2. pp. 251-259. (2020)

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Abstract

The present study arose from the need of to determine inorganic arsenic (iAs) at low levels in rice. Ultra-high performance liquid chromatography coupled with inductively coupled plasma mass spectrometry (UHPLC-ICPMS) using Kinetic Energy Discrimination (KED) mode to eliminate spectral interferences was used for analysis of iAs. Sample preparation involves extraction of inorganic arsenic (sum of As3+ and As5+) with water by heating at 90 °C for 5 min in water bath. Separation is accomplished with a reversed-phase ion pack column using a gradient chromatographic method followed by ICPMS analysis within 5 min. The method was validated in accordance with Commission Regulation (EU) No 836/2011 and performance characteristics were verifi ed. Acceptable values were obtained for specifi city, repeatability (HorRatr < 0.6), within-lab reproducibility (HorRatR < 0.3) with recovery 80-90%, limit of quantifi cation (0.02 mg/ kg), fi tness-for-purpose and trueness (using CRM); thus, the method can be considered for offi cial control purposes.

Item Type: Article
Journal or Publication Title: Acta biologica Szegediensis
Date: 2020
Volume: 64
Number: 2
ISSN: 1588-4082
Page Range: pp. 251-259
Language: English
Related URLs: http://acta.bibl.u-szeged.hu/73049/
DOI: 10.14232/abs.2020.2.251-259
Uncontrolled Keywords: Biológia, Kémia
Additional Information: Bibliogr.: p. 257-259. ; összefoglalás angol nyelven
Subjects: 01. Natural sciences
01. Natural sciences > 01.04. Chemical sciences
01. Natural sciences > 01.06. Biological sciences
Date Deposited: 2021. Jul. 15. 16:00
Last Modified: 2021. Jul. 15. 16:00
URI: http://acta.bibl.u-szeged.hu/id/eprint/73075

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