"Smart" molecular engineering of metallomesogens based on Pt(II) terpyridine coordination complexes

Popa Evelyn and Heinrich Benoît and Andelescu Adelina A. and Deda Massimo La and Maio Giuseppe Di and Voirin Emilie and Donnio Bertrand and Szerb Elisabeta I.: "Smart" molecular engineering of metallomesogens based on Pt(II) terpyridine coordination complexes.

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Abstract

A series of ionic tetracoordinated Pt(II) complexes based on terpyridine ligand were synthesized and characterized. Their chemical structures were engineered by using counterions of different coordination strengths and dimensions, namely non-coordinating BF4, weakly coordinating bulky gallate units, and small and strongly coordinating chlorine (Cl). The complexes containing lipophilic gallate units exhibit low temperature liquid crystalline properties. The mesomorphic properties were investigated by polarized optical microscopy (POM), differential scanning calorimetry (DSC) and X-ray diffraction studies (SWAXS). Photophysical properties were determined in solution and condensed states.

Item Type: Conference or Workshop Item
Journal or Publication Title: Proceedings of the International Symposium on Analytical and Environmental Problems
Date: 2020
Volume: 26
ISBN: 978-963-306-771-0
Page Range: pp. 40-42
Language: English
Event Title: International Symposium on Analytical and Environmental Problems (26.) (2020) (Szeged)
Related URLs: http://acta.bibl.u-szeged.hu/73792/
Uncontrolled Keywords: Környezetkémia
Additional Information: Bibliogr.: 42. p. ; összefoglalás angol nyelven
Subjects: 01. Natural sciences
01. Natural sciences > 01.04. Chemical sciences
Date Deposited: 2021. Nov. 16. 13:32
Last Modified: 2022. Aug. 08. 15:39
URI: http://acta.bibl.u-szeged.hu/id/eprint/73947

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