Optimization of dispersive liquid-liquid microextraction for polyethylene glycol-coated gold and silver nanoparticles

Torregrosa Daniel and Grindlay Guillermo and Ungor Ditta and Csapó Edit and Galbács Gábor: Optimization of dispersive liquid-liquid microextraction for polyethylene glycol-coated gold and silver nanoparticles.

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Abstract

The use of polyethylene glycol modified nanoparticles is becoming an interesting topic since they present a very good stability in biological media. However, the effects of these nanoparticles on organisms are still unclear, so it is necessary to monitor their presence in bodily fluids, such as plasma or urine. Single-particle ICP-MS is a versatile tool to simultaneously detect and characterize nanoparticles in aqueous media, but a previous extraction step is necessary when analyzing complex samples due to the occurrence of matrix effects. In this work, an ultrasound assisted dispersive liquid-liquid microextraction method based on the use of chloroform as extracting solvent has been optimized for the extraction, characterization, and quantification of polyethylene glycol modified gold and silver nanoparticles in aqueous media. So far, we could achieve extraction efficiencies higher than 75% for both types of nanoparticles studied. We believe that with further optimization, the extraction can be made quantitative.

Item Type:	Conference or Workshop Item
Journal or Publication Title:	Proceedings of the International Symposium on Analytical and Environmental Problems
Date:	2021
Volume:	27
ISBN:	978-963-306-835-9
Page Range:	pp. 343-347
Language:	English
Publisher:	University of Szeged
Place of Publication:	Szeged
Event Title:	International Symposium on Analytical and Environmental Problems (27.) (2021) (Szeged)
Related URLs:	http://acta.bibl.u-szeged.hu/75798/
Uncontrolled Keywords:	Analitikai kémia
Additional Information:	Bibliogr.: 347. p. ; ill. ; összefoglalás angol nyelven
Subjects:	01. Natural sciences 01. Natural sciences > 01.04. Chemical sciences
Date Deposited:	2022. Jun. 01. 10:36
Last Modified:	2022. Aug. 08. 15:40
URI:	http://acta.bibl.u-szeged.hu/id/eprint/76002

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