Novel copper complexes with glyoximes, amines, schiff bases, semi-and thiosemicarbazones ; synthesis and physico-chemical analysis

Várhelyi Csaba and Szalay Roland and Pokol György and Madarász János and Szilágyi Imre Miklós and Huszthy Péter and Simon-Várhelyi Melinda and Tötös Róbert and Mereu Raluca-Anca and Avram Alexandra and Korecz László and May Nóra V. and Mihály Judith: Novel copper complexes with glyoximes, amines, schiff bases, semi-and thiosemicarbazones ; synthesis and physico-chemical analysis.

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Abstract

In our research project new copper(II) complexes were synthesized with -dioximes, amines, Schiff bases, semi- and thiosemicarbazones such as [Cu(DioxH)2L2], (DioxH2: methyl-butylglyoxime, ethyl-butyl-glyoxime, methyl-phenyl-glyoxime; L: diphenyl-amine, 2-methylimidazole, dibutyl-amine, 2-amino-4-methylpyridine, imidazole, 1-aminonaphthaline), [Cu(octan-2-one)2AL2], (A: hydrazine, phenylhydrazine, o-phenylene-diamine; L: 3-amino1H-1,2,4-triazole, 2-aminopyrimidine, 2-methylimidazole), [Cu(ketone-SC)2], [Cu(ketoneTSC)2], (ketone: propiophenone, butyrophenone; SC: semicarbazone; TSC: thiosemicarbazone), by the reaction of copper(II)-acetate in suitable solvent. After a short bibliographical survey, involving the classification and evolution of copper complexes with possible applications, we analyzed their physicochemical properties using FTIR, Raman, ESR, UV-VIS, powder X-ray diffraction (XRD), mass spectrometry, thermal analysis (TG, DTG, DTA) and SEM. The importance of this class of compounds lies in biochemistry as some of them are antibacterial agents and potential anti-tumour drugs.

Item Type: Conference or Workshop Item
Journal or Publication Title: Proceedings of the International Symposium on Analytical and Environmental Problems
Date: 2022
Volume: 28
ISBN: 978-963-306-904-2
Page Range: pp. 46-50
Language: English
Place of Publication: Szeged
Event Title: 28th International Symposium on Analytical and Environmental Problems
Event Type: Conference
Event Location: Szeged
Event Dates: 2022. november 14-15.
Related URLs: https://acta.bibl.u-szeged.hu/78308/
Uncontrolled Keywords: Fizikai kémia, Analitikai kémia
Additional Information: Bibliogr.: 50. p. ; összefoglalás angol nyelven
Subjects: 01. Natural sciences
01. Natural sciences > 01.04. Chemical sciences
Date Deposited: 2023. Mar. 16. 15:21
Last Modified: 2023. Mar. 16. 15:21
URI: http://acta.bibl.u-szeged.hu/id/eprint/78456

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