Đurović Ana; Stojanović Zorica; Kravić Snežana; Rakić Dušan; Grahovac Nada: Chronopotentiometric determination of metamitron comparing classical and Box-Behnken optimization approaches.
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This paper describes an optimization procedure for determination of the herbicide metamitron by chronopotentiometry. Two different working electrodes were use in the experiments: glassy carbon and thin film mercury electrode. The analytical signal of metamitron was the result of irreversible reduction on the working electrodes in Britton-Robinson buffer as the supporting electrolyte, and one reduction peak was obtained on both working electrodes. Operating conditions, involving several chemical and instrumental parameters such as: pH of Britton-Robinson buffer, initial potential and reduction current were optimized by the classical method, where one parameter is changing while others are constant, and by using Box-Behnken experimental design. In both optimization procedures, the maximum height of the metamitron analytical signal was requested. Obtained results from this study revealed that there were no differences between the two optimization methods.
| Mű típusa: | Konferencia vagy workshop anyag |
|---|---|
| Befoglaló folyóirat/kiadvány címe: | Proceedings of the International Symposium on Analytical and Environmental Problems |
| Dátum: | 2018 |
| Kötet: | 24 |
| ISBN: | 978-963-306-623-2 |
| Oldalak: | pp. 110-114 |
| Konferencia neve: | International Symposium on Analytical and Environmental Problems (24.) (2018) (Szeged) |
| Befoglaló mű URL: | http://acta.bibl.u-szeged.hu/55895/ |
| Kulcsszavak: | Agrokémia |
| Megjegyzések: | Bibliogr.: p. 113-114. ; összefoglalás angol nyelven |
| Feltöltés dátuma: | 2019. jan. 04. 08:52 |
| Utolsó módosítás: | 2022. aug. 08. 15:50 |
| URI: | http://acta.bibl.u-szeged.hu/id/eprint/56294 |
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